It is not yet known whether Brad's wife Angelina Jolie will be joining her family at the match.
The Liverpool Echo reports that the Fury and Snatch star is going to be on Merseyside this weekend.
Brad became a Liverpool fan when his son Maddox was taken to Alder Hey Children's Hospital in 2002 after falling ill while Angelina filmed Tomb Raider in nearby North Wales.
Brad and Angelina are far from the Reds' only celebrity fans.
Sex And The City star Kim Cattrall, Austin Powers actor Mike Myers, tennis player Caroline Wozniacki and Pulp Fiction star Samuel L. Jackson are all big Liverpool supporters.
Another surprise fan of Brendan Rodgers' side is award-winning singer Lana Del Rey.
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